On the kinetics of lithium-initiated anionic polymerization in nonpolar solvents
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چکیده
منابع مشابه
Kinetics of Living Anionic Polymerization of Polystyrenyl Lithium in Cyclohexane
Living anionic polymer chains polymerized with organolithium initiators usually form aggregates through their Li ends in nonpolar solvents. This aggregation structure strongly affects the anionic polymerization (propagation) kinetics. In the conventional molecular picture, the aggregates are assumed to be chemically inert and the propagation occurs only though the dissociated unimers, which lea...
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ژورنال
عنوان ژورنال: Journal of Polymer Science Part A: Polymer Chemistry
سال: 1997
ISSN: 0887-624X,1099-0518
DOI: 10.1002/(sici)1099-0518(19971130)35:16<3613::aid-pola29>3.0.co;2-h